Motion of rotatory molecular motor and chemical reaction rate
نویسندگان
چکیده
We examine the dependence of the physical quantities of the rotatory molecular motor, such as the rotation velocity and the proton translocation rate, on the chemical reaction rate using the model based only on diffusion process. A peculiar behavior of proton translocation is found and the energy transduction efficiency of the motor protein is enhanced by this behavior. We give a natural explanation that this behavior is universal when certain inequalities between chemical reaction rates hold. That may give a clue to examine whether the motion of the molecular motor is dominated by diffusion process or not.
منابع مشابه
Pump process of the rotatory molecular motor and its energy efficiency
The pump process of the ratchet model inspired by the Fo rotatory motor of ATP synthase is investigated. In this model there are two kinds of characteristic time. One is dynamical, the relaxation time of the system. Others are chemical, the chemical reaction rates at which a proton binds to or dissociates from the motor protein. The inequalities between them affect the behavior of the physical ...
متن کاملThe Contribution of Molecular Diffusion in Silica Coating and Chemical Reaction in the Overall Rate of Reaction of Aluminum Hydroxide with Fluosilicic Acid
The kinetic of the heterogeneous chemical reaction of aluminum hydroxide and fluosilicic acid was studied. It was found that the diffusion of the reactants through the porous silica coating to the aluminum hydroxide surface and the interfacial chemical reaction between the diffusing reactant and aluminum hydroxide platelets control the overall reaction rate. These two phenomena were studied...
متن کاملChemical and mechanical efficiencies of molecular motors and implications for motor mechanisms.
Molecular motors operate in an environment dominated by viscous friction and thermal fluctuations. The chemical reaction in a motor may produce an active force at the reaction site to directly move the motor forward. Alternatively a molecular motor may generate a unidirectional motion by rectifying thermal fluctuations using free energy barriers established in the chemical reaction. The reactio...
متن کاملMathematical theory of molecular motors and a new approach for uncovering motor mechanism.
Molecular motors operate in an environment dominated by thermal fluctuations. A molecular motor may produce an active force at the reaction site to directly move the motor forward. Alternatively a molecular motor may generate a unidirectional motion by rectifying thermal fluctuations. In this case, the chemical reaction establishes free energy barriers to block the backward fluctuations. The ef...
متن کاملSynthesis and identification of polystyrene via conventional and controlled radical polymerization methods: Effect of temperature, initiator and transfer agent on molecular weight and reaction rate
Polystyrene (PSt) has been known as one of the important polymers with a wide range of applications. Ability to synthesize PSt with different but predictable molecular weights for various applications is very important in the laboratories and industries. In this study, using various simple and inexpensive techniques with only free radical mechanism, it was tried to synthesize PSt with different...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره شماره
صفحات -
تاریخ انتشار 2003